Dr. Caroline Marchi Delapierre

Date du document : 17 décembre 2013
Dernière mise à jour le : 18 février 2014

caroline.marchi-delapierre@cea.fr

Education / Graduation / Career

  • 1996 - University Paul Cézanne, Marseille - Master of Chemistry
  • 1999 - University Paul Cézanne, Marseille - PhD in Organic Chemistry
  • 1997-1999 - Autonom University of Barcelona - Post-Doctoral Position

Teaching: The main disciplines

  • Organic Chemistry
  • Inorganic Chemistry
  • Biochemistry

Research Topics

  • Catalysis with artificial Metalloenzymes
  • Iron oxidation catalysis

Publications

  • An artificial oxygenase built from scratch : substrate binding site identified using a docking approach" Esmieu, C. ; Cherrier, M. V. ; Amara, P. ; Girgenti, E. ; Marchi-Delapierre, C. ; Oddon, F. ; Iannello, M. ; Jorge-Robin, A. ; Cavazza, C. ; Ménage, S. Angew. Chem., Int. Ed. 2013, 52 (14), 3922-3925.
  • The structure of the periplasmic nickel-binding protein NikA provides insights for artificial metalloenzyme design” Cherrier, M. V. ; Girgenti, E. ; Amara, P. ; Iannello, M. ; Marchi-Delapierre, C. ; Fontecilla-Camps, J.- C. ; Ménage, S. ; Cavazza, C. J. Biol. Inorg. Chem. 2012, 17(5), 817-829.
  • Iron Coordination Chemistry of N2Py2 ligand substituted by carboxylic moieties and their impact on Alkene Oxidation Catalysis.” Oddon, F. ; Girgenti, E. ; Lebrun, C. ; Marchi-Delapierre, C. ; Pécaut, J. ; Ménage, S. Eur. J ; Inorg. Chem. 2012, 1, 85-96.
  • Clear-cut difference in the rearrangement of 1-bromo-2-(2-phenyl-3-butenyl)benzene under anionic or radical conditions” Reynaud, C.; Hazimeh, H.; Mattalia, J.-M.; Marchi-Delapierre, C.; Chanon, M. ARKIVOC 2011, 33-43.
  • Crystallographic snapshots of the reaction of aromatic C-H with O2 catalyzed by a protein-bound iron complex.” Cavazza, C.; Bochot, C.; Rousselot-Pailley, P.; Carpentier, P.; Cherrier, M.V.; Martin, L.; Marchi-Delapierre, C.; Fontecilla-Camps, J.C.; Ménage, S. Nature Chem. 2010, 2(12), 1069-76.
  • The Protein Environment Drives Selectivity for Sulfide Oxidation by an Artificial Metalloenzyme“ Rousselot-Pailley, P., Bochot, C.; Marchi-Delapierre, C.; Jorge-Robin, A.; Martin, L.; Fontecilla-Camps, J. C.; Cavazza, C.; Menage, S. CHEMBIOCHEM 2009, 10(3), 545-552.
  • A new chiral diiron catalyst for enantioselective epoxidation” C. Marchi-Delapierre, A. Jorge-Robin, A. Thibon and S. Ménage, Chem. Commun., 2007,1166-1168.
  • Radical Clocks and Electron Transfer. Compared Crown Ether Effects in the Reactivity of Potassium and Magnesium towards 1-bromo-2-but-3-énylbenzene. The incidence of homogeneous versus heterogeneous electron transfer on selectivity.” Hazimeh, H.; Mattalia, J.-M.; Marchi-Delapierre, C.; Barone, R.; Nudelman, N.S.; Chanon, M. J. Phys. Org. Chem. 2005, 18, 1145-60.
  • Ni(II)-Catalyzed Michael Additions (II). Dynamic Kinetic Resolution in the Reduction of Chiral ?-Hydrazino-?-ketoacid Derivatives” Marchi, C.; Trepat, E.; Moreno-Mañas, M.; Vallribera, A.; Molins, E. Tetrahedron 2002, 58, 5689-5708.
  • Diastereoselectivity of Borane Addition to Chiral Triquinphosphoranes. NMR, X-rays and Molecular Modelling Studies" Marchi, C.; Fotiadu, F.; Buono, G. Organometallics 1999, 18(5), 915-927.

Interests, Projects, Ideas

 

External links